Earth's Systems / Biological processes / Terrestrial ecosystem functioning / Living soil system / Volcanic ash parent material, short-range-order minerals and Andosol carbon

Volcanic ash parent material, short-range-order minerals and Andosol carbon

Volcanic ash weathers quickly into poorly crystalline minerals such as allophane and ferrihydrite that bind organic matter and phosphate strongly, giving Andosols very high carbon storage and phosphorus fixation.

Boundary: where this process starts

Starts with: Fresh ash and tephra (volcanic glass) falls and weathers within decades in humid climates

Boundary: where it ends

Ends after: In wet climates over millennia allophane crystallises to halloysite and Fe oxides and the carbon protection weakens; Strong phosphate retention (andic criteria: oxalate Al + half Fe at least 2%, bulk density 0.9 g/cm3 or less, P retention at least 85%) fixes phosphorus

PARTICIPANTSRESOURCESAllophaneVolcanic ashAluminumSoil organicmatterFerrihydriteAluminumSilicaIron oxidesVolcanic ashWaterImpact +3 of 5. Click for details and evidence.Impact +4 of 5. Click for details and evidence.Impact +4 of 5. Click for details and evidence.Impact +3 of 5. Click for details and evidence.Impact -2 of 5. Click for details and evidence.Impact -3 of 5. Click for details and evidence.Impact -3 of 5. Click for details and evidence.Impact +4 of 5. Click for details and evidence.Impact +3 of 5. Click for details and evidence.↻ reinforces · moderate · 0.25 Organic matteFresh ash and tephra (volcanic glass) falls and weathers within decades in humid climates: makes AluminummakesFresh ash and tephra (volcanic glass) falls and weathers within decades in humid climates: makes SilicamakesFresh ash and tephra (volcanic glass) falls and weathers within decades in humid climates: uses up Volcanic ashuses upFresh ash and tephra (volcanic glass) falls and weathers within decades in humid climates: uses WaterReleased Al and Si precipitate as allophane, imogolite and ferrihydrite instead of crystalline clay: uses up Aluminumuses upReleased Al and Si precipitate as allophane, imogolite and ferrihydrite instead of crystalline clay: uses up Silicauses upReleased Al and Si precipitate as allophane, imogolite and ferrihydrite instead of crystalline clay: makes Iron oxidesmakesAllophane and Al-humus complexes bind organic matter so strongly that Andosols hold large Soil organic matter stocks with slow turnover: uses AluminumStrong phosphate retention (andic criteria: oxalate Al + half Fe at least 2%, bulk density 0.9 g/cm3 or less, P retention at least 85%) fixes phosphorus: uses AluminumStrong phosphate retention (andic criteria: oxalate Al + half Fe at least 2%, bulk density 0.9 g/cm3 or less, P retention at least 85%) fixes phosphorus: uses Iron oxidesIn wet climates over millennia allophane crystallises to halloysite and Fe oxides and the carbon protection weakens: uses SilicaIn wet climates over millennia allophane crystallises to halloysite and Fe oxides and the carbon protection weakens: makes Iron oxidesmakesreleased by weatheringAluminum: released by weatheringreleased by weatheringSilica: released by weatheringweathers within decadesVolcanic ash: weathers within decadesdrives humid weatheringWater: drives humid weatheringprecipitated asshort-range mineralsAluminum: precipitated as short-range mineralsprecipitated asshort-range mineralsSilica: precipitated as short-range mineralsform as ferrihydriteIron oxides: form as ferrihydritebinds organic matterAluminum: binds organic mattersorbs phosphateAluminum: sorbs phosphatesorb phosphate withaluminumIron oxides: sorb phosphate with aluminumcrystallises intohalloysiteSilica: crystallises into halloysiteform as allophaneweathersIron oxides: form as allophane weathersStart: Volcanic ashparent material,short-range-ord…STARTStart: Volcanic ash parent material, short-range-order minerals and Andosol carbonEnd: Volcanic ashparent material,short-range-ord…ENDEnd: Volcanic ash parent material, short-range-order minerals and Andosol carbonFresh ash and tephra(volcanic glass) fallsand weathers with…📄1 ↗1Fresh ash and tephra (volcanic glass) falls and weathers within decades in humid climatesReleased Al and Siprecipitate asallophane, imogoli…📄1Released Al and Si precipitate as allophane, imogolite and ferrihydrite instead of crystalline clayAllophane and Al-humuscomplexes bind organicmatter so strongly th…📄1Allophane and Al-humus complexes bind organic matter so strongly that Andosols hold large Soil organic matter stocks with slow turnoverStrong phosphateretention (andiccriteria: oxalate Al…📄1Strong phosphate retention (andic criteria: oxalate Al + half Fe at least 2%, bulk density 0.9 g/cm3 or less, P retention at least 85%) fixes phosphorusIn wet climates overmillennia allophanecrystallises …📄1In wet climates over millennia allophane crystallises to halloysite and Fe oxides and the carbon protection weakens
Line thickness = size of impact (1 to 5)% on a line = chance a fork takes that branch📄 = pieces of evidence on a stepNegative effectLoops backHypothesisResource used up (arrow into the step)Resource used, not used upResource made or released (arrow out of the step)
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Loop
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Size of impact
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Every step, with its evidence

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Fresh ash and tephra (volcanic glass) falls and weathers within decades in humid climates
Evidence (1) · added by Cinder
  • Shoji, Nanzyo & Dahlgren (1993) Volcanic Ash Soils, Elsevier: Volcanic glass is far more weatherable than crystalline silicates. (confidence 0.8)
Released Al and Si precipitate as allophane, imogolite and ferrihydrite instead of crystalline clay
Evidence (1) · added by Cinder
  • Wada (1989) in Dixon & Weed (eds) Minerals in Soil Environments, 2nd ed., SSSA, ch. 21, Allophane and imogolite: Allophane (Si:Al about 0.5-1) forms where Si activity is moderate and pH is above about 5; Al-humus complexes form at lower pH. (confidence 0.75)
Allophane and Al-humus complexes bind organic matter so strongly that Andosols hold large Soil organic matter stocks with slow turnover
Evidence (1) · added by Cinder
  • Torn et al. (1997) Nature 389:170-173, Mineral control of soil organic carbon storage and turnover: Across a Hawaiian volcanic-ash chronosequence, soil carbon and its 14C turnover time track the amount of noncrystalline minerals, not climate. (confidence 0.85)
Strong phosphate retention (andic criteria: oxalate Al + half Fe at least 2%, bulk density 0.9 g/cm3 or less, P retention at least 85%) fixes phosphorus
Evidence (1) · added by Cinder
  • Soil Survey Staff (2014) Keys to Soil Taxonomy, 12th ed., andic soil properties: Andic properties require oxalate-extractable Al + 1/2 Fe of at least 2.0%, bulk density of 0.90 g/cm3 or less and phosphate retention of 85% or more. (confidence 0.8)
In wet climates over millennia allophane crystallises to halloysite and Fe oxides and the carbon protection weakens
Evidence (1) · added by Cinder
  • Torn et al. (1997) Nature 389:170-173; Shoji et al. (1993): Noncrystalline phases decline and crystalline clay and oxides rise on the oldest, wettest sites; carbon storage falls with them. (confidence 0.65)